论文类型：Research Article
第一作者：Liang,Jiashun
通讯作者：Li,Qing
合写作者：Huang,Yunhui,Wu,Lu,Gang,Wang,Hsing-Lin,Zhang,Siyang,Shi,Hao,Xia,Yu,Wan,Yangyang,Liu,Xuan,Li,Shenzhou
发表刊物：Nature Catalysis
所属单位：华中科技大学
刊物所在地：英国
卷号：7
期号：6
页面范围：719-732
ISSN号：2520-1158
关键字：Electrocatalysis; Energy; Nanowires
DOI码：10.1038/s41929-024-01167-8
发表时间：2024-06-23
影响因子：42.8
摘要：The preparation of noble metal nanowire electrocatalysts is greatly limited by the thermodynamically symmetric growth of face-centred-cubic structures. Here we report a gas-balancing adsorption strategy to prepare ultrathin palladium-, platinum- and gold-based nanowires (diameter < 2 nm) by controlling the competitive adsorption of in situ-generated H2 and CO. We prepare a library of 43 nanowires consisting of the three above-mentioned noble metals as hosts and 14 metals as guests. The ternary Pd85Pt8Ni7H41 nanowires with interstitial hydrogen exhibit impressive mass and specific activities of and 13.9 mA cm−2, respectively, for the oxygen reduction reaction at 0.9 VRHE in alkali. Operando X-ray absorption spectroscopy demonstrates breathing-like Pd–Pd bond length and strain changes at the applied potential, with Pd85Pt8Ni7H41 nanowires exhibiting larger compressive strain at relevant potentials, as well as low oxygen coverage. Theoretical calculations suggest that the interstitial hydrogen induces an s–d orbital interaction between palladium and hydrogen, which enhances the activity of the oxygen reduction reaction. The Pd85Pt8Ni7H41 nanowires can generate a high power density of 0.87 W cm−2 in H2/air (CO2-free) at 70 °C in an anion-exchange membrane fuel cell.