论文类型：Research Article
第一作者：Liang, Jiashun
通讯作者：Huang,Xiaoqing,Huang,Bolong,Bu,Lingzheng,Li,Qing
合写作者：Zhou,Xiaochun,Ma,Yanhang,Zhan,Changhong,Sun,Mingzi,Huang,Ju,Ning,Fandi
发表刊物：Advanced Materials
所属单位：华中科技大学
刊物所在地：美国
文献类型：Article
卷号：35
期号：11
页面范围：2208672
ISSN号：1521-4095
关键字：Fuel Cells; Low Coordination; Membrane Electrode Assembly; Nanosaws; Oxygen Reduction Reaction
DOI码：10.1002/adma.202208672
发表时间：2022-12-27
影响因子：27.4
摘要：Developing high-performance catalysts for fuel cell catalysis is the most critical and challenging step for the commercialization of fuel cell technology. Here 1D trimetallic platinum–iron–cobalt nanosaws (Pt3FeCo NSs) with low-coordination features are designed as efficient bifunctional electrocatalysts for practical fuel cell catalysis. The oxygen reduction reaction (ORR) activity of Pt3FeCo NSs (10.62 mA cm−2 and 4.66 A mg−1Pt at 0.90 V) is more than 25-folds higher than that of the commercial Pt/C, even after 30 000 voltage cycles. Density functional theory calculations reveal that the strong inter-d-orbital electron transfer minimizes the ORR barrier with higher selectivity at robust valence states. The volcano correlation between the intrinsic structure featured with low-coordination Pt-sites and corresponding electronic activities is discovered, which guarantees high ORR activities. The Pt3FeCo NSs located in the membrane electrode assembly (MEA) also achieve very high peak power density (1800.6 mW cm−2) and competitive specific/mass activities (1.79 mA cm−2 and 0.79 A mg−1Pt at 0.90 ViR-free cell voltage) as well as a long-term lifetime in specific H2O2 medium for proton-exchange-membrane fuel cells, ranking top electrocatalysts reported to date for MEA. This work represents a class of multimetallic Pt-based nanocatalysts for practical fuel cells and beyond.