Microscopic Structure‐Property Relation of Metal‐Organic Polyhedron Nanocomposites
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论文类型:期刊论文
第一作者:Mingxin Zhang
通讯作者:Caili Huang*, Panchao Yin*
合写作者: Yuyan Lai, Mu Li, Tao Hong, Weiyu Wang, Haitao Yu, Lengwan Li, Qianjie Zhou, Yubin Ke, Xiaozhi Zhan, Tao Zhu, Caili Huang,*,Panchao Yin*
发表刊物:Angewante Chemie International Edition
收录刊物:SCI
文献类型:J
卷号:58
页面范围:17412–17417
发表时间:2019-09-23
摘要:Monodispersed hairy nanocomposites system with typical 2‐nm (isophthalic acid) 24 Cu 24 metal‐organic polyhedron (MOP) as core protected by 24 polymer chains with controlled narrow molecular weight distribution has been experimentally probed by imaging and scattering studies for the heterogeneity of polymers in the nanocomposites and the confinement effect the MOPs imposing to anchored polymers. Typical confined‐extending surrounded by one entanglement area is proposed to picture the physical states of polymer chains. This model dictates the counterintuitive thermal and rheological properties
发布期刊链接:https://onlinelibrary.wiley.com/doi/10.1002/anie.201909241
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