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Infrared spectrum and its implications for the electronic structure of the semiconducting iron selenide K0.83Fe1.53Se2

发布时间:2023-09-05  点击次数:
论文类型:期刊论文 第一作者:ZG Chen 合写作者:NL Wang,XL Chen,JG Guo,JL Luo,P Zheng,YG Shi,G Xu,T Dong,RH Yuan 发表刊物:Physical Review B 收录刊物:SCI 学科门类:物理学 文献类型:J 卷号:83 期号:22 页面范围:220507 ISSN号:2469-9950 发表时间:2011-06-16 影响因子:3.691 摘要:We report an infrared spectroscopy study on K 0. 83 Fe 1. 53 Se 2, a semiconducting parent compound of the 245 iron selenide superconductors. The major spectral features are found to be distinctly different from all other Fe-based superconducting systems. Our measurement revealed two peculiar spectral structures: a double-peak structure between 4000 and 6000 cm− 1 and abundant phonon modes—much more than expected for a 122 structure. We elaborate that those features could be naturally explained from the blocked antiferromagnetism due to the presence of Fe vacancy ordering as determined by recent neutron-diffraction experiments. The double peaks reflect the coexistence of ferromagnetic and antiferromagnetic couplings between the neighboring Fe sites. 发布期刊链接:https://journals.aps.org/prb/abstract/10.1103/PhysRevB.83.220507